Magnetization transfer from protons to quadrupolar nuclei in solid-state NMR using PRESTO or dipolar-mediated refocused INEPT methods
نویسندگان
چکیده
منابع مشابه
New methods and applications in solid-state NMR spectroscopy of quadrupolar nuclei.
Solid-state nuclear magnetic resonance (NMR) spectroscopy has long been established as offering unique atomic-scale and element-specific insight into the structure, disorder, and dynamics of materials. NMR spectra of quadrupolar nuclei (I > (1)/2) are often perceived as being challenging to acquire and to interpret because of the presence of anisotropic broadening arising from the interaction o...
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Historically, cross-polarization experiments [1,2] have been used to transfer spin coherence from abundant spins to a dilute spin system. Protons (*H) have been used almost exclusively as the source of strong nuclear polarization for cross-polarization experiments, although there have been some examples where other abundant nuclei have been used. Coupled with magic-angle spinning (MAS) NMR [3],...
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Several different amplitude-modulated two-dimensional high-resolution methods, based on MQMAS and STMAS, are compared. They include 3QMAS, 5QMAS, DQ-STMAS, and DQF-STMAS experiments. A new method, called t1-split-STMAS, is also proposed for spin-3/2 nuclei. The comparison is performed in terms of isotropic resolution and spectral-width, efficiency, and sensitivity to magic-angle offset and spin...
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Nonsecular dipolar couplings between spin2 nuclei that are in close proximity to quadrupolar spins have been extensively documented in solid state nuclear magnetic resonance ~NMR!, particularly when involving directly bonded S5C, I5N spin pairs. These couplings arise due to the quadrupole-induced tilting of I’s nuclear spin quantization axes, and their most notable characteristic is that they c...
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A sensitivity enhancement method based on selective adiabatic inversion of a satellite transition has been employed in a (pi/2)CT-(pi)ST1-(pi/2)CT spectral editing sequence to both enhance and resolve multisite NMR spectra of quadrupolar nuclei. In addition to a total enhancement of 2.5 times for spin 3/2 nuclei, enhancements up to 2.0 times is reported for the edited sites in a mixture of rubi...
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ژورنال
عنوان ژورنال: Journal of Magnetic Resonance
سال: 2019
ISSN: 1090-7807
DOI: 10.1016/j.jmr.2018.12.016